Organophosphorus (V) Chemistry : Organophosphorus (V) Chemistry.

By: Timperley, Chris
Publisher: London : Elsevier Science & Technology, 2014Copyright date: ©2014Description: 1 online resource (787 pages)Content type: text Media type: computer Carrier type: online resourceISBN: 9780080982243Subject(s): Organophosphorus compoundsGenre/Form: Electronic books. Additional physical formats: Print version:: Organophosphorus (V) Chemistry : Organophosphorus (V) ChemistryDDC classification: 547.07 LOC classification: QD412.P1 -- .T567 2015ebOnline resources: Click to View
Contents:
Front Cover -- Best Synthetic Methods -- OTHER VOLUMES IN THE SERIES -- Best Synthetic Methods -- Copyright -- CONTENTS -- CONTRIBUTORS -- PREFACE -- EXEMPTION -- ACKNOWLEDGEMENTS -- REFERENCES -- Chapter 1 - General Overview -- 1.1 INTRODUCTION -- 1.2 NATURAL OCCURRENCE OF PHOSPHORUS -- 1.3 PRINCIPAL COMPOUNDS OF PHOSPHORUS -- 1.4 PHOSPHORUS COMPOUNDS IN LIVING SYSTEMS -- 1.5 A BRIEF HISTORY OF SYNTHETIC ORGANOPHOSPHORUS CHEMISTRY -- 1.5.3 ORGANOPHOSPHORUS PESTICIDES -- 1.6 NOMENCLATURE OF ORGANOPHOSPHORUS COMPOUNDS -- 1.7 CHIRAL PHOSPHORUS COMPOUNDS AND BIOLOGICAL IMPLICATIONS -- 1.8 PHOSPHORUS-CONTAINING PHARMACEUTICALS -- 1.9 FIRE RETARDANTS AND FIRE-EXTINGUISHING COMPOUNDS -- 1.10 TOXICOLOGY AND MEDICAL TREATMENT OF ORGANOPHOSPHORUS COMPOUNDS -- 1.11 FLUOROGENIC NERVE AGENT MIMICS FOR SCREENING FOR IMPROVED BIOSCAVENGERS -- 1.12 BIOTINYLATED NERVE AGENT MIMICS FOR ACTIVITY-BASED ENZYME PROFILING -- 1.13 WORKING SAFELY WITH ORGANOPHOSPHORUS COMPOUNDS -- REFERENCES -- Chapter 2 - Phosphonyl Compounds -- 2.1 INTRODUCTION -- 2.2 ALKYL ALKYL-H-PHOSPHINATES R(R′O)P(O)H -- 2.3 ALKYLPHOSPHONIC DICHLORIDES RP(O)CL2 -- 2.4 ALKYLPHOSPHONIC DIBROMIDES RP(O)BR2 -- 2.5 ALKYLPHOSPHONIC DIFLUORIDES RP(O)F2 -- 2.6 ALKYLPHOSPHONOFLUORIDIC ACIDS RP(O)(OH)F -- 2.7 ALKYLPHOSPHONIC CHLOROFLUORIDES RP(O)CIF -- 2.8 ALKYLPHOSPHONIC ISOCYANATOFLUORIDES RP(O)(NCO)F -- 2.9 ALKYLPHOSPHONIC ISOTHIOCYANATOFLUORIDES RP(O)(NCS)F -- 2.10 ALKYLPHOSPHONIC DIISOCYANATES RP(O)(NCO)2 -- 2.11 ALKYLPHOSPHONIC DIISOTHIOCYANATES RP(O)(NCS)2 -- 2.12 ALKYLPHOSPHONIC ACIDS RP(O)(OH)2 -- 2.13 DIALKYL ALKYLPHOSPHONATES RP(O)(OR)2 -- 2.14 DIALKYL ARYLPHOSPHONATES ARP(O)(OR)2 -- 2.15 DIALKYL α-KETOPHOSPHONATES (RO)2P(O)C(O)R′ -- 2.16 DIALKYL α-HYDROXYPHOSPHONATES (RO)2P(O)CH(OH)R′ (PUDOVIK REACTION) -- 2.17 DIALKYL α-SILOXYPHOSPHONATES (RO)2P(O)CH(OSIME3)R′ (ABRAMOV REACTION).
2.18 DIALKYL α-AMINOPHOSPHONATES (RO)2P(O)CR2NR2 (KABACHNIK-FIELDS REACTION) -- 2.19 DIALKYL ALKENYLPHOSPHONATES (RO)2P(O)CCR2 -- 2.20 DIALKYL ALKYNYLPHOSPHONATES (RO)2P(O)C≡CR -- 2.21 ALKYL ALKYLPHOSPHONOCHLORIDATES R(R′O)P(O)CL -- 2.22 N,N-DIALKYL ALKYLPHOSPHONAMIDOCHLORIDATES R(R′2N)P(O)CL -- 2.23 S-ALKYL ALKYLPHOSPHONOCHLORIDOTHIOLATES R(R′S)P(O)CL -- 2.24 ALKYL ALKYLPHOSPHONOFLUORIDATES R(R′O)P(O)F -- 2.25 N-ALKYL OR N,N-DIALKYL ALKYLPHOSPHONAMIDOFLUORIDATES R(R′XN)P(O)F (X=H OR R′) -- 2.26 S-ALKYL ALKYLPHOSPHONOFLUORIDOTHIOLATES R(R′S)P(O)F -- 2.27 ALKYL ALKYLPHOSPHONOCYANIDATES R(R′O)P(O)CN -- 2.28 ALKYL ALKYLPHOSPHONIC ACIDS R(R′O)P(O)OH -- 2.29 ALKYLPHOSPHONOFLUORIDIC ANHYDRIDES R(F)P(O)OP(O)(F)R -- 2.30 DIALKYL DIALKYLPYROPHOSPHONATES R(R′O)P(O)OP(O)(OR′)R -- 2.31 N,N-DIALKYL-P-ALKYLPHOSPHONAMIDIC ANHYDRIDES R(R′2N)P(O)OP(O)(NR′2)R -- 2.32 S,S′-DIALKYL DIALKYLDITHIOPYROPHOSPHONATES R(R′S)P(O)OP(O)(SR′)R -- 2.33 O-ALKYL N-ALKYL ALKYLPHOSPHONAMIDATES RP(O)(NR2)OR -- 2.34 BIS(N,N-DIALKYL) ALKYLPHOSPHONODIAMIDATES RP(O)(NR2)2 -- 2.35 O,S-DIALKYL ALKYLPHOSPHONOTHIOLATES RP(O)(OR)SR -- 2.36 S-ALKYL N-ALKYL (OR N,N-DIALKYL) ALKYLPHOSPHONAMIDOTHIOLATES RP(O)(NR2)SR -- 2.37 S,S′-DIALKYL ALKYLPHOSPHONODITHIOLATES RP(O)(SR2)2 -- REFERENCES -- Chapter 3 - Thiophosphonyl Compounds -- 3.1 INTRODUCTION -- 3.2 ALKYLPHOSPHONOTHIOIC DICHLORIDES RP(S)CL2 -- 3.3 ALKYLPHOSPHONOTHIOIC DIFLUORIDES RP(S)F2 -- 3.4 DIALKYL ALKYLPHOSPHONOTHIONATES (RO)2P(S)R -- 3.5 ALKYL ALKYLPHOSPHONOCHLORIDOTHIONATES RO(R′)P(S)CL -- 3.6 ALKYL ALKYLPHOSPHONOFLUORIDOTHIONATES RO(R′)P(S)F -- 3.7 O-ALKYL HYDROGEN ALKYLPHOSPHONOTHIOATES RO(R′)P(S)OH -- 3.8 DIALKYL DIALKYLPYROPHOSPHONODITHIONATES RO(R′)P(S)OP(S)(R′)OR -- 3.9 S-ALKYL ALKYLPHOSPHONOCHLORIDOTHIOLOTHIONATES RS(R′)P(S)CL -- 3.10 N,N-DIALKYL P-ALKYLPHOSPHONAMIDOCHLORIDOTHIONATES R2N(R′)P(S)CL.
3.11 N,N-DIALKYL P-ALKYLPHOSPHONAMIDOFLUORIDOTHIONATES R2N(R′)P(S)F -- 3.12 ALKYL ALKYLPHOSPHONOCYANIDOTHIONATES RO(R′)P(S)CN -- 3.13 ALKYL ALKYL/ARYL ALKYLPHOSPHONOTHIONATES RO(R′)P(S)OR′′ -- 3.14 O-ALKYL N-ALKYL/ARYL ALKYLPHOSPHONAMIDOTHIONATES RO(R′)P(S)NR2 -- 3.15 O-ALKYL S-ALKYL ALKYLPHOSPHONODITHIOATES RO(R′)P(S)SR -- 3.16 BIS(O-ALKYL ALKYLPHOSPHINOTHIOYL) DISULFIDES RO(R′)P(S)SSP(S)(R′)OR -- 3.17 BIS(N,N-DIALKYL) ALKYLPHOSPHONODIAMIDOTHIONATES (R2N)2P(S)R′ -- 3.18 S,S′-DIALKYL ALKYLPHOSPHONODITHIOLOTHIONATES (RS)2P(S)R′ -- REFERENCES -- Chapter 4 - Phosphoryl Compounds -- 4.1 INTRODUCTION -- 4.2 ALKYL PHOSPHORODICHLORIDATES ROP(O)CL2 -- 4.3 ARYL PHOSPHORODICHLORIDATES AROP(O)CL2 -- 4.4 ALKYL PHOSPHORODIFLUORIDATES ROP(O)F2 -- 4.5 ARYL PHOSPHORODIFLUORIDATES AROP(O)F2 -- 4.6 ALKYL N,N,N′,N′-TETRAALKYL PHOSPHORODIAMIDATES ROP(O)(NR2)2 -- 4.7 ALKYL PHOSPHORODIHYDRAZIDATES ROP(O)(NHNHR)2 -- 4.8 ALKYL PHOSPHORODIISOCYANATIDATES ROP(O)(NCO)2 -- 4.9 ALKYL PHOSPHORODIISOTHIOCYANATIDATES ROP(O)(NCS)2 -- 4.10 ALKYL DIHYDROGEN PHOSPHATES ROP(O)(OH)2 -- 4.11 O,S,S′-TRIALKYL PHOSPHORODITHIOLATES ROP(O)(SR)2 -- 4.12 O,S-DIALKYL PHOSPHOROCHLORIDOTHIOLATES RO(RS)P(O)CL -- 4.13 O-ALKYL N,N-DIALKYLPHOSPHORAMIDOCHLORIDATES RO(R2N)P(O)CL -- 4.14 S-ALKYL N,N-DIALKYLPHOSPHORAMIDOCHLORIDOTHIOLATES RS(R2N)P(O)CL -- 4.15 S,S′-DIALKYL PHOSPHOROCHLORIDODITHIOLATES (RS)2P(O)CL -- 4.16 O,S-DIALKYL PHOSPHOROFLUORIDOTHIOLATES RO(RS)P(O)F -- 4.17 O-ALKYL N,N-DIALKYLPHOSPHORAMIDOFLUORIDATES RO(R2N)P(O)F -- 4.18 SYMMETRICAL DIALKYL H-PHOSPHONATES (RO)2P(O)H -- 4.19 UNSYMMETRICAL DIALKYL H-PHOSPHONATES RO(R′O)P(O)H -- 4.20 DIARYL H-PHOSPHONATES (ARO)2P(O)H -- 4.21 DIALKYL PHOSPHOROFLUORIDATES (RO)2P(O)F -- 4.22 DIALKYL PHOSPHOROCHLORIDATES (RO)2P(O)CL -- 4.23 DIARYL PHOSPHOROCHLORIDATES (ARO)2P(O)CL -- 4.24 DIALKYL PHOSPHOROBROMIDATES (RO)2P(O)BR.
4.25 DIALKYL PHOSPHOROIODIDATES (RO)2P(O)I -- 4.26 DIALKYL PHOSPHOROCYANIDATES (RO)2P(O)CN -- 4.27 O-ALKYL DIALKOXYPHOSPHINYLFORMATES (RO)2P(O)C(O)OR -- 4.28 S-ALKYL DIALKOXYPHOSPHINYLTHIOFORMATES (RO)2P(O)C(O)SR -- 4.29 N-ALKYL DIALKOXYPHOSPHINYLFORMAMIDES (RO)2P(O)C(O)NR2 -- 4.30 [(DIALKOXYPHOSPHINYL)FORMYL]-O-ALKYLHYDROXAMATES (RO)2P(O)C(O)NHOR -- 4.31 S-ALKYL DIALKOXYPHOSPHINYLDITHIOFORMATES (RO)2P(O)C(S)SR -- 4.32 SYMMETRICAL DIALKYL HYDROGEN PHOSPHATES (RO)2P(O)OH -- 4.33 UNSYMMETRICAL DIALKYL HYDROGEN PHOSPHATES RO(R′O)P(O)OH -- 4.34 DIALKYL ALKYLPEROXY PHOSPHATES (RO)2P(O)OOR -- 4.35 TRIALKYL PHOSPHATES (RO)2P(O)OR -- 4.36 DIARYL ALKYL PHOSPHATES (ARO)2P(O)OR -- 4.37 TRIARYL PHOSPHATES (ARO)3PO -- 4.38 DIALKYL ALKYLIDENEAMINO PHOSPHATES (RO)2P(O)ONCR2 (ALLEN REACTION) -- 4.39 DIALKYL ENOLPHOSPHATES (RO)2P(O)OCRCR2 (PERKOW REACTION) -- 4.40 DIALKYL PHOSPHORAZIDATES (RO)2P(O)N3 -- 4.41 DIALKYL PHOSPHORAMIDATES (RO)2P(O)NR2 (TODD-ATHERTON REACTION) -- 4.42 DIALKYL N-ARYLPHOSPHORAMIDATES (RO)2P(O)NHAR -- 4.43 DIARYL PHOSPHORAMIDATES (ARO)2P(O)NR2 -- 4.44 DIALKYL N-METHYL-N-(PHOSPHORYL)PHOSPHORAMIDATES (RO)2P(O)N(ME)P(X)R2 -- 4.45 DIALKYL N-METHYL-N-ACYLPHOSPHORAMIDATES (RO)2P(O)N(ME)COR′ -- 4.46 DISUBSTITUTED N-ARYL(OR ALKYL)-N-CHLOROPHOSPHORAMIDATES (RO)2P(O)N(CL)AR -- 4.47 DIALKYL N,N-DIHALOPHOSPHORAMIDATES (RO)2P(O)NX2 (X=CL OR BR) -- 4.48 DIALKYL N-HYDROXY/ALKOXYPHOSPHORAMIDATES (RO)2P(O)NHOR (R=H OR ALKYL) -- 4.49 DIALKYL PHOSPHOROHYDRAZIDATES (RO)2P(O)NH2NH2 -- 4.50 DIALKYL PHOSPHOROISOCYANATIDATES (RO)2P(O)NCO -- 4.51 DIALKYL PHOSPHOROISOTHIOCYANATIDATES (RO)2P(O)NCS -- 4.52 DIALKYL PHOSPHORO(THIONYLAMIDATES) (RO)2P(O)NSO -- 4.53 N,N′-BIS(DIALKYLPHOSPHORYL)SULFAMIDES (RO)2P(O)NHSO2NHP(O)(OR)2 -- 4.54 N-(DIALKYLPHOSPHORYL)ALDIMINES (RO)2P(O)NCHR -- 4.55 N-(DIALKYLPHOSPHORYL)GUANIDINES (RO)2P(O)NC(NR2)2.
4.56 O,O-DIALKYL HYDROGEN PHOSPHOROTHIOATES (RO)2P(O)SH -- 4.57 O,O,S-TRIALKYL PHOSPHOROTHIOLATES (RO)2P(O)SR -- 4.58 DIALKYL S-(S-ALKYL) PHOSPHOROTHIOLATES (RO)2P(O)SSR -- 4.59 DIALKYL S-(O-ALKYL) PHOSPHOROTHIOLATES (RO)2P(O)SOR -- 4.60 DIALKYLPHOSPHORYL ALKYLSULFONATES (RO)2P(O)S(O)OR -- 4.61 TETRAALKYL PYROPHOSPHATES (RO)2P(O)OP(O)(OR)2 -- 4.62 BIS(DIALKYLPHOSPHORYL) SULFIDES (RO)2P(O)SP(O)(OR)2 -- 4.63 BIS(DIALKYLPHOSPHORYL) DISULFIDES (RO)2P(O)SSP(O)(OR)2 -- 4.64 BIS(DIALKYLPHOSPHORYL) SULFOXIDES (RO)2P(O)S(O)P(O)(OR)2 -- 4.65 N-ALKYLPHOSPHORAMIDIC DICHLORIDES RNHP(O)CL2 -- 4.66 N,N-DIALKYLPHOSPHORAMIDIC DICHLORIDES R2NP(O)CL2 -- 4.67 N,N-DIALKYLPHOSPHORAMIDIC DIFLUORIDES R2NP(O)F2 -- 4.68 N,N,N′,N′-TETRAALKYL PHOSPHORODIAMIDITES (R2N)2P(O)H -- 4.69 N,N,N′,N′-TETRAALKYL PHOSPHORODIAMIDOCHLORIDATES (R2N)2P(O)CL -- 4.70 BIS(N-ALKYL) OR N,N,N′,N′-TETRAALKYL PHOSPHORODIAMIDOFLUORIDATES (R2N)2P(O)F -- 4.71 N,N,N′,N′-TETRAALKYL PHOSPHORODIAMIDOAZIDATES (R2N)2P(O)N3 -- 4.72 BIS(N,N-DIALKYL) PYROPHOSPHORODIAMIDATES (R2N)2P(O)OP(O)(NR2)2 -- 4.73 TRI- AND HEXAALKYLPHOSPHORAMIDES (RNH)3PO AND (R2N)3PO -- REFERENCES -- Chapter 5 - Thiophosphoryl Compounds -- 5.1 INTRODUCTION -- 5.2 ALKYL PHOSPHORODICHLORIDOTHIONATES ROP(S)CL2 -- 5.3 DIALKYL H-THIOPHOSPHONATES (RO)2P(S)H -- 5.4 DIALKYL PHOSPHOROCHLORIDOTHIONATES (RO)2P(S)CL -- 5.5 DIALKYL PHOSPHOROCYANIDOTHIONATES (RO)2P(S)CN -- 5.6 O,O-DIALKYL HYDROGEN PHOSPHOROTHIOATES (RO)2P(S)OH -- 5.7 TRIALKYL (OR DIALKYL ARYL) PHOSPHOROTHIONATES (RO)2P(S)OR′ -- 5.8 DIALKYL ENOL PHOSPHOROTHIONATES (RO)2P(S)OCRCR2′ -- 5.9 O,O-DIALKYL O-OXIMINO PHOSPHOROTHIONATES (RO)2P(S)ONCR2′ -- 5.10 O,O-DIALKYL O-ACYL PHOSPHOROTHIONATES (RO)2P(S)OC(O)R′ -- 5.11 DIALKYL PHOSPHORAMIDOTHIONATES (RO)2P(S)NH2 -- 5.12 S,S-DIALKYL PHOSPHORAMIDODITHIOLOTHIONATES (RS)2P(S)NHR′ -- 5.13 TRIS(N,N-DIALKYLAMINO)PHOSPHOROTHIONATES (R2N)3PS.
5.14 DISUBSTITUTED N-(ALKOXY)PHOSPHORAMIDOTHIONATES (RO)2P(S)NHOR′.
Summary: Best Synthetic Methods: ORGANOPHOSPHORUS (V) CHEMISTRY provides systematic coverage of the most common classes of pentavalent organophosphorus compounds and reagents (including phosphonyl, phosphoryl, and organophosphates), and allows researchers an easy point of entry into this complex and economically important field. The book follows the Best Synthetic Methods format, containing practical methods, synthetic tips, and shortcuts. Where relevant, articles include toxicity data and historical context for the reactions. Typical analytical and spectroscopic data are also presented to enable scientists to identify key compound characteristics. The book is a valuable companion to research chemists in both academia and industry, summarizing the best practical methods (often originating in difficult-to-access, foreign-language primary literature) in one place. It is ideally suited for those working on industrial applications of these compounds, including insecticides, herbicides, flame retardants, and plasticizers. Includes a mixture of tried and tested, historical methods that are proven to work, alongside new methods to provide scientists with a quick, time-saving resource of reliable methods Includes tips and tricks to get reactions to work; important information often missing from other sources Includes key analytical data for compounds, so scientists have one handy resource to select, perform, and analyze the best reaction.
Item type Current location Call number Status Date due Barcode Item holds
Ebrary Ebrary Afghanistan
Available EBKAF-N000725
Ebrary Ebrary Algeria
Available
Ebrary Ebrary Cyprus
Available
Ebrary Ebrary Egypt
Available
Ebrary Ebrary Libya
Available
Ebrary Ebrary Morocco
Available
Ebrary Ebrary Nepal
Available EBKNP-N000725
Ebrary Ebrary Sudan

Access a wide range of magazines and books using Pressreader and Ebook central.

Enjoy your reading, British Council Sudan.

Available
Ebrary Ebrary Tunisia
Available
Total holds: 0

Front Cover -- Best Synthetic Methods -- OTHER VOLUMES IN THE SERIES -- Best Synthetic Methods -- Copyright -- CONTENTS -- CONTRIBUTORS -- PREFACE -- EXEMPTION -- ACKNOWLEDGEMENTS -- REFERENCES -- Chapter 1 - General Overview -- 1.1 INTRODUCTION -- 1.2 NATURAL OCCURRENCE OF PHOSPHORUS -- 1.3 PRINCIPAL COMPOUNDS OF PHOSPHORUS -- 1.4 PHOSPHORUS COMPOUNDS IN LIVING SYSTEMS -- 1.5 A BRIEF HISTORY OF SYNTHETIC ORGANOPHOSPHORUS CHEMISTRY -- 1.5.3 ORGANOPHOSPHORUS PESTICIDES -- 1.6 NOMENCLATURE OF ORGANOPHOSPHORUS COMPOUNDS -- 1.7 CHIRAL PHOSPHORUS COMPOUNDS AND BIOLOGICAL IMPLICATIONS -- 1.8 PHOSPHORUS-CONTAINING PHARMACEUTICALS -- 1.9 FIRE RETARDANTS AND FIRE-EXTINGUISHING COMPOUNDS -- 1.10 TOXICOLOGY AND MEDICAL TREATMENT OF ORGANOPHOSPHORUS COMPOUNDS -- 1.11 FLUOROGENIC NERVE AGENT MIMICS FOR SCREENING FOR IMPROVED BIOSCAVENGERS -- 1.12 BIOTINYLATED NERVE AGENT MIMICS FOR ACTIVITY-BASED ENZYME PROFILING -- 1.13 WORKING SAFELY WITH ORGANOPHOSPHORUS COMPOUNDS -- REFERENCES -- Chapter 2 - Phosphonyl Compounds -- 2.1 INTRODUCTION -- 2.2 ALKYL ALKYL-H-PHOSPHINATES R(R′O)P(O)H -- 2.3 ALKYLPHOSPHONIC DICHLORIDES RP(O)CL2 -- 2.4 ALKYLPHOSPHONIC DIBROMIDES RP(O)BR2 -- 2.5 ALKYLPHOSPHONIC DIFLUORIDES RP(O)F2 -- 2.6 ALKYLPHOSPHONOFLUORIDIC ACIDS RP(O)(OH)F -- 2.7 ALKYLPHOSPHONIC CHLOROFLUORIDES RP(O)CIF -- 2.8 ALKYLPHOSPHONIC ISOCYANATOFLUORIDES RP(O)(NCO)F -- 2.9 ALKYLPHOSPHONIC ISOTHIOCYANATOFLUORIDES RP(O)(NCS)F -- 2.10 ALKYLPHOSPHONIC DIISOCYANATES RP(O)(NCO)2 -- 2.11 ALKYLPHOSPHONIC DIISOTHIOCYANATES RP(O)(NCS)2 -- 2.12 ALKYLPHOSPHONIC ACIDS RP(O)(OH)2 -- 2.13 DIALKYL ALKYLPHOSPHONATES RP(O)(OR)2 -- 2.14 DIALKYL ARYLPHOSPHONATES ARP(O)(OR)2 -- 2.15 DIALKYL α-KETOPHOSPHONATES (RO)2P(O)C(O)R′ -- 2.16 DIALKYL α-HYDROXYPHOSPHONATES (RO)2P(O)CH(OH)R′ (PUDOVIK REACTION) -- 2.17 DIALKYL α-SILOXYPHOSPHONATES (RO)2P(O)CH(OSIME3)R′ (ABRAMOV REACTION).

2.18 DIALKYL α-AMINOPHOSPHONATES (RO)2P(O)CR2NR2 (KABACHNIK-FIELDS REACTION) -- 2.19 DIALKYL ALKENYLPHOSPHONATES (RO)2P(O)CCR2 -- 2.20 DIALKYL ALKYNYLPHOSPHONATES (RO)2P(O)C≡CR -- 2.21 ALKYL ALKYLPHOSPHONOCHLORIDATES R(R′O)P(O)CL -- 2.22 N,N-DIALKYL ALKYLPHOSPHONAMIDOCHLORIDATES R(R′2N)P(O)CL -- 2.23 S-ALKYL ALKYLPHOSPHONOCHLORIDOTHIOLATES R(R′S)P(O)CL -- 2.24 ALKYL ALKYLPHOSPHONOFLUORIDATES R(R′O)P(O)F -- 2.25 N-ALKYL OR N,N-DIALKYL ALKYLPHOSPHONAMIDOFLUORIDATES R(R′XN)P(O)F (X=H OR R′) -- 2.26 S-ALKYL ALKYLPHOSPHONOFLUORIDOTHIOLATES R(R′S)P(O)F -- 2.27 ALKYL ALKYLPHOSPHONOCYANIDATES R(R′O)P(O)CN -- 2.28 ALKYL ALKYLPHOSPHONIC ACIDS R(R′O)P(O)OH -- 2.29 ALKYLPHOSPHONOFLUORIDIC ANHYDRIDES R(F)P(O)OP(O)(F)R -- 2.30 DIALKYL DIALKYLPYROPHOSPHONATES R(R′O)P(O)OP(O)(OR′)R -- 2.31 N,N-DIALKYL-P-ALKYLPHOSPHONAMIDIC ANHYDRIDES R(R′2N)P(O)OP(O)(NR′2)R -- 2.32 S,S′-DIALKYL DIALKYLDITHIOPYROPHOSPHONATES R(R′S)P(O)OP(O)(SR′)R -- 2.33 O-ALKYL N-ALKYL ALKYLPHOSPHONAMIDATES RP(O)(NR2)OR -- 2.34 BIS(N,N-DIALKYL) ALKYLPHOSPHONODIAMIDATES RP(O)(NR2)2 -- 2.35 O,S-DIALKYL ALKYLPHOSPHONOTHIOLATES RP(O)(OR)SR -- 2.36 S-ALKYL N-ALKYL (OR N,N-DIALKYL) ALKYLPHOSPHONAMIDOTHIOLATES RP(O)(NR2)SR -- 2.37 S,S′-DIALKYL ALKYLPHOSPHONODITHIOLATES RP(O)(SR2)2 -- REFERENCES -- Chapter 3 - Thiophosphonyl Compounds -- 3.1 INTRODUCTION -- 3.2 ALKYLPHOSPHONOTHIOIC DICHLORIDES RP(S)CL2 -- 3.3 ALKYLPHOSPHONOTHIOIC DIFLUORIDES RP(S)F2 -- 3.4 DIALKYL ALKYLPHOSPHONOTHIONATES (RO)2P(S)R -- 3.5 ALKYL ALKYLPHOSPHONOCHLORIDOTHIONATES RO(R′)P(S)CL -- 3.6 ALKYL ALKYLPHOSPHONOFLUORIDOTHIONATES RO(R′)P(S)F -- 3.7 O-ALKYL HYDROGEN ALKYLPHOSPHONOTHIOATES RO(R′)P(S)OH -- 3.8 DIALKYL DIALKYLPYROPHOSPHONODITHIONATES RO(R′)P(S)OP(S)(R′)OR -- 3.9 S-ALKYL ALKYLPHOSPHONOCHLORIDOTHIOLOTHIONATES RS(R′)P(S)CL -- 3.10 N,N-DIALKYL P-ALKYLPHOSPHONAMIDOCHLORIDOTHIONATES R2N(R′)P(S)CL.

3.11 N,N-DIALKYL P-ALKYLPHOSPHONAMIDOFLUORIDOTHIONATES R2N(R′)P(S)F -- 3.12 ALKYL ALKYLPHOSPHONOCYANIDOTHIONATES RO(R′)P(S)CN -- 3.13 ALKYL ALKYL/ARYL ALKYLPHOSPHONOTHIONATES RO(R′)P(S)OR′′ -- 3.14 O-ALKYL N-ALKYL/ARYL ALKYLPHOSPHONAMIDOTHIONATES RO(R′)P(S)NR2 -- 3.15 O-ALKYL S-ALKYL ALKYLPHOSPHONODITHIOATES RO(R′)P(S)SR -- 3.16 BIS(O-ALKYL ALKYLPHOSPHINOTHIOYL) DISULFIDES RO(R′)P(S)SSP(S)(R′)OR -- 3.17 BIS(N,N-DIALKYL) ALKYLPHOSPHONODIAMIDOTHIONATES (R2N)2P(S)R′ -- 3.18 S,S′-DIALKYL ALKYLPHOSPHONODITHIOLOTHIONATES (RS)2P(S)R′ -- REFERENCES -- Chapter 4 - Phosphoryl Compounds -- 4.1 INTRODUCTION -- 4.2 ALKYL PHOSPHORODICHLORIDATES ROP(O)CL2 -- 4.3 ARYL PHOSPHORODICHLORIDATES AROP(O)CL2 -- 4.4 ALKYL PHOSPHORODIFLUORIDATES ROP(O)F2 -- 4.5 ARYL PHOSPHORODIFLUORIDATES AROP(O)F2 -- 4.6 ALKYL N,N,N′,N′-TETRAALKYL PHOSPHORODIAMIDATES ROP(O)(NR2)2 -- 4.7 ALKYL PHOSPHORODIHYDRAZIDATES ROP(O)(NHNHR)2 -- 4.8 ALKYL PHOSPHORODIISOCYANATIDATES ROP(O)(NCO)2 -- 4.9 ALKYL PHOSPHORODIISOTHIOCYANATIDATES ROP(O)(NCS)2 -- 4.10 ALKYL DIHYDROGEN PHOSPHATES ROP(O)(OH)2 -- 4.11 O,S,S′-TRIALKYL PHOSPHORODITHIOLATES ROP(O)(SR)2 -- 4.12 O,S-DIALKYL PHOSPHOROCHLORIDOTHIOLATES RO(RS)P(O)CL -- 4.13 O-ALKYL N,N-DIALKYLPHOSPHORAMIDOCHLORIDATES RO(R2N)P(O)CL -- 4.14 S-ALKYL N,N-DIALKYLPHOSPHORAMIDOCHLORIDOTHIOLATES RS(R2N)P(O)CL -- 4.15 S,S′-DIALKYL PHOSPHOROCHLORIDODITHIOLATES (RS)2P(O)CL -- 4.16 O,S-DIALKYL PHOSPHOROFLUORIDOTHIOLATES RO(RS)P(O)F -- 4.17 O-ALKYL N,N-DIALKYLPHOSPHORAMIDOFLUORIDATES RO(R2N)P(O)F -- 4.18 SYMMETRICAL DIALKYL H-PHOSPHONATES (RO)2P(O)H -- 4.19 UNSYMMETRICAL DIALKYL H-PHOSPHONATES RO(R′O)P(O)H -- 4.20 DIARYL H-PHOSPHONATES (ARO)2P(O)H -- 4.21 DIALKYL PHOSPHOROFLUORIDATES (RO)2P(O)F -- 4.22 DIALKYL PHOSPHOROCHLORIDATES (RO)2P(O)CL -- 4.23 DIARYL PHOSPHOROCHLORIDATES (ARO)2P(O)CL -- 4.24 DIALKYL PHOSPHOROBROMIDATES (RO)2P(O)BR.

4.25 DIALKYL PHOSPHOROIODIDATES (RO)2P(O)I -- 4.26 DIALKYL PHOSPHOROCYANIDATES (RO)2P(O)CN -- 4.27 O-ALKYL DIALKOXYPHOSPHINYLFORMATES (RO)2P(O)C(O)OR -- 4.28 S-ALKYL DIALKOXYPHOSPHINYLTHIOFORMATES (RO)2P(O)C(O)SR -- 4.29 N-ALKYL DIALKOXYPHOSPHINYLFORMAMIDES (RO)2P(O)C(O)NR2 -- 4.30 [(DIALKOXYPHOSPHINYL)FORMYL]-O-ALKYLHYDROXAMATES (RO)2P(O)C(O)NHOR -- 4.31 S-ALKYL DIALKOXYPHOSPHINYLDITHIOFORMATES (RO)2P(O)C(S)SR -- 4.32 SYMMETRICAL DIALKYL HYDROGEN PHOSPHATES (RO)2P(O)OH -- 4.33 UNSYMMETRICAL DIALKYL HYDROGEN PHOSPHATES RO(R′O)P(O)OH -- 4.34 DIALKYL ALKYLPEROXY PHOSPHATES (RO)2P(O)OOR -- 4.35 TRIALKYL PHOSPHATES (RO)2P(O)OR -- 4.36 DIARYL ALKYL PHOSPHATES (ARO)2P(O)OR -- 4.37 TRIARYL PHOSPHATES (ARO)3PO -- 4.38 DIALKYL ALKYLIDENEAMINO PHOSPHATES (RO)2P(O)ONCR2 (ALLEN REACTION) -- 4.39 DIALKYL ENOLPHOSPHATES (RO)2P(O)OCRCR2 (PERKOW REACTION) -- 4.40 DIALKYL PHOSPHORAZIDATES (RO)2P(O)N3 -- 4.41 DIALKYL PHOSPHORAMIDATES (RO)2P(O)NR2 (TODD-ATHERTON REACTION) -- 4.42 DIALKYL N-ARYLPHOSPHORAMIDATES (RO)2P(O)NHAR -- 4.43 DIARYL PHOSPHORAMIDATES (ARO)2P(O)NR2 -- 4.44 DIALKYL N-METHYL-N-(PHOSPHORYL)PHOSPHORAMIDATES (RO)2P(O)N(ME)P(X)R2 -- 4.45 DIALKYL N-METHYL-N-ACYLPHOSPHORAMIDATES (RO)2P(O)N(ME)COR′ -- 4.46 DISUBSTITUTED N-ARYL(OR ALKYL)-N-CHLOROPHOSPHORAMIDATES (RO)2P(O)N(CL)AR -- 4.47 DIALKYL N,N-DIHALOPHOSPHORAMIDATES (RO)2P(O)NX2 (X=CL OR BR) -- 4.48 DIALKYL N-HYDROXY/ALKOXYPHOSPHORAMIDATES (RO)2P(O)NHOR (R=H OR ALKYL) -- 4.49 DIALKYL PHOSPHOROHYDRAZIDATES (RO)2P(O)NH2NH2 -- 4.50 DIALKYL PHOSPHOROISOCYANATIDATES (RO)2P(O)NCO -- 4.51 DIALKYL PHOSPHOROISOTHIOCYANATIDATES (RO)2P(O)NCS -- 4.52 DIALKYL PHOSPHORO(THIONYLAMIDATES) (RO)2P(O)NSO -- 4.53 N,N′-BIS(DIALKYLPHOSPHORYL)SULFAMIDES (RO)2P(O)NHSO2NHP(O)(OR)2 -- 4.54 N-(DIALKYLPHOSPHORYL)ALDIMINES (RO)2P(O)NCHR -- 4.55 N-(DIALKYLPHOSPHORYL)GUANIDINES (RO)2P(O)NC(NR2)2.

4.56 O,O-DIALKYL HYDROGEN PHOSPHOROTHIOATES (RO)2P(O)SH -- 4.57 O,O,S-TRIALKYL PHOSPHOROTHIOLATES (RO)2P(O)SR -- 4.58 DIALKYL S-(S-ALKYL) PHOSPHOROTHIOLATES (RO)2P(O)SSR -- 4.59 DIALKYL S-(O-ALKYL) PHOSPHOROTHIOLATES (RO)2P(O)SOR -- 4.60 DIALKYLPHOSPHORYL ALKYLSULFONATES (RO)2P(O)S(O)OR -- 4.61 TETRAALKYL PYROPHOSPHATES (RO)2P(O)OP(O)(OR)2 -- 4.62 BIS(DIALKYLPHOSPHORYL) SULFIDES (RO)2P(O)SP(O)(OR)2 -- 4.63 BIS(DIALKYLPHOSPHORYL) DISULFIDES (RO)2P(O)SSP(O)(OR)2 -- 4.64 BIS(DIALKYLPHOSPHORYL) SULFOXIDES (RO)2P(O)S(O)P(O)(OR)2 -- 4.65 N-ALKYLPHOSPHORAMIDIC DICHLORIDES RNHP(O)CL2 -- 4.66 N,N-DIALKYLPHOSPHORAMIDIC DICHLORIDES R2NP(O)CL2 -- 4.67 N,N-DIALKYLPHOSPHORAMIDIC DIFLUORIDES R2NP(O)F2 -- 4.68 N,N,N′,N′-TETRAALKYL PHOSPHORODIAMIDITES (R2N)2P(O)H -- 4.69 N,N,N′,N′-TETRAALKYL PHOSPHORODIAMIDOCHLORIDATES (R2N)2P(O)CL -- 4.70 BIS(N-ALKYL) OR N,N,N′,N′-TETRAALKYL PHOSPHORODIAMIDOFLUORIDATES (R2N)2P(O)F -- 4.71 N,N,N′,N′-TETRAALKYL PHOSPHORODIAMIDOAZIDATES (R2N)2P(O)N3 -- 4.72 BIS(N,N-DIALKYL) PYROPHOSPHORODIAMIDATES (R2N)2P(O)OP(O)(NR2)2 -- 4.73 TRI- AND HEXAALKYLPHOSPHORAMIDES (RNH)3PO AND (R2N)3PO -- REFERENCES -- Chapter 5 - Thiophosphoryl Compounds -- 5.1 INTRODUCTION -- 5.2 ALKYL PHOSPHORODICHLORIDOTHIONATES ROP(S)CL2 -- 5.3 DIALKYL H-THIOPHOSPHONATES (RO)2P(S)H -- 5.4 DIALKYL PHOSPHOROCHLORIDOTHIONATES (RO)2P(S)CL -- 5.5 DIALKYL PHOSPHOROCYANIDOTHIONATES (RO)2P(S)CN -- 5.6 O,O-DIALKYL HYDROGEN PHOSPHOROTHIOATES (RO)2P(S)OH -- 5.7 TRIALKYL (OR DIALKYL ARYL) PHOSPHOROTHIONATES (RO)2P(S)OR′ -- 5.8 DIALKYL ENOL PHOSPHOROTHIONATES (RO)2P(S)OCRCR2′ -- 5.9 O,O-DIALKYL O-OXIMINO PHOSPHOROTHIONATES (RO)2P(S)ONCR2′ -- 5.10 O,O-DIALKYL O-ACYL PHOSPHOROTHIONATES (RO)2P(S)OC(O)R′ -- 5.11 DIALKYL PHOSPHORAMIDOTHIONATES (RO)2P(S)NH2 -- 5.12 S,S-DIALKYL PHOSPHORAMIDODITHIOLOTHIONATES (RS)2P(S)NHR′ -- 5.13 TRIS(N,N-DIALKYLAMINO)PHOSPHOROTHIONATES (R2N)3PS.

5.14 DISUBSTITUTED N-(ALKOXY)PHOSPHORAMIDOTHIONATES (RO)2P(S)NHOR′.

Best Synthetic Methods: ORGANOPHOSPHORUS (V) CHEMISTRY provides systematic coverage of the most common classes of pentavalent organophosphorus compounds and reagents (including phosphonyl, phosphoryl, and organophosphates), and allows researchers an easy point of entry into this complex and economically important field. The book follows the Best Synthetic Methods format, containing practical methods, synthetic tips, and shortcuts. Where relevant, articles include toxicity data and historical context for the reactions. Typical analytical and spectroscopic data are also presented to enable scientists to identify key compound characteristics. The book is a valuable companion to research chemists in both academia and industry, summarizing the best practical methods (often originating in difficult-to-access, foreign-language primary literature) in one place. It is ideally suited for those working on industrial applications of these compounds, including insecticides, herbicides, flame retardants, and plasticizers. Includes a mixture of tried and tested, historical methods that are proven to work, alongside new methods to provide scientists with a quick, time-saving resource of reliable methods Includes tips and tricks to get reactions to work; important information often missing from other sources Includes key analytical data for compounds, so scientists have one handy resource to select, perform, and analyze the best reaction.

Description based on publisher supplied metadata and other sources.

Electronic reproduction. Ann Arbor, Michigan : ProQuest Ebook Central, 2019. Available via World Wide Web. Access may be limited to ProQuest Ebook Central affiliated libraries.

There are no comments for this item.

to post a comment.